The Corsair VX series are basically the Seasonic S12 inside
The HX are the Seasonic M12 (ie modular version)
Now the thing about multiple rails is that they are often not that seperate at all.
In most cases what it actually is is a single 12v feed being feed to multiple solder points on the pcb inside the psu, which may have additional bridges between them.
The upshot of all this is reduced heat&load stress, reduced noise and overall improved stability/load smoothing.
However that doesn't mean all multiple rail designs are better than single rail or that all multiple rail psu's follow the same system.
Have a look at http://www.jonnyguru.com/ they do some very detailed PSU reviews esp concerning the insides.