Pre 1900 buildings are unlikely to have cavity walls. They will usually be solid masonry, either brick or stone depending on where you live.
Adding anything to the wall will alter its breathability and due point. You may actually worsen the problem rather than solve it. An architect will be able to calculate the wall's properties quite easily.
Mould once into the plaster can only ever be got rid of by removing the plaster entirely, treating the wall behind it and replastering. Short-term a surface treatment of the plaster to kill the visible mould and coating with mould resistant paints will work, but the mould will eventually get through it so it's a time vs cost vs maintenance over time balance.
Check the drains and roof are in good repair and not leaking into or onto the wall. Eg a blocked gutter causing water to run down the wall.
Check also that the room is being ventilated appropriately and not too humid. Any en-suite showers been added? A dehumidifier may be required to control the air moisture content in the room.
Repointing the brickwork will help as most penetration of water will be through the mortar joints I imagine. The age of the building suggests a lime mortar will have been used. The repair should therefore be in a lime mortar also. Overpointing lime mortar with a cement mortar is a very bad idea and will actually cause damage to the wall in the long run.


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