A while back when I was slowly moving over to 775 (via an ASRock motherboard) I went from a athlon xp2400+ & 6800LE (unlocked&clocked to GT level) to a Pentium D 3ghz and geforce2mx on a 350w psu, I tried it with the 6800LE but it couldn't cope.
I then upped the PSU to a 470w thermaltake TR2 (420w continuous and only 14a+15a on the 12v) which let me use both pentium D & 6800LE
Theos temp numbers sound about right The pentium D does run hot, just keep it under 60c full load and you should be fine.
PS which 6800LE do you have? I had the leadtec one which had the added advantage of coming with the same heatsink leadtec used on the 6800GT a humongous lump of copper on both sides of the card