Firstly is your PSU this
one?
If it is it seems it's not modular and all the cables should be with the PSU as it's specs say it should have x2 PCie 6 and x2 PCIe 6+2 cables. So you might have connected them already either from seperate cables or using the non modular cables
Secondly in regards with the cross fire issue, if you get a second card same class but different model i.e another 6870 but it is lower in clock speed, the highest your system will use is the lowest Clock speed and that goes for both cards. So your effectively wasting your higher clocked card for e.g. Generally try and get the same brand and model of card.
Your PSU is more than enough for crossfire 6870
My other question is, why do you need to go Crossfire? do you have low fps on playing games, or want want to play at the highest detail or do you plan on using more than 1 monitor for e.g