Well, each to their own. I'd rather give the few quid a week directly to charity, without the lottery tax along the way. The odds are so long as to be ridiculous, not to mention unexciting (to me, at least).
Besides, surely the better thing to do is to just go to a bookies and bet that you can guess this week's lottery numbers. Then, if you get it right, you're guaranteed to be getting ~£10+ million (13,983,816 to 1 odds, right?) rather than sharing the pot. No idea if this is actually possible, but certainly seems like the better way of doing things to me.