From what little I know of using the motherboard to control fans, you go into BIOS and select either PWM or DC control. It can't do both,
AFAIK.
So that'd mean getting another DC fan for the rear, or upgrading your whole cooling profile... Personally I'd do the latter, but that's just me. Phanteks generally make quite food fans, so I might look to get more of the same model from them... If you prefer, Noctua are good, as are some Corsair fans. Arctic are almost as good as Noctua, but made and consequently sold somewhat cheaper.
You could just move the rear fan forward and forget any other fans.
This would create positive pressure, and air would then exhaust through any existing gaps - You can remove the empty PCIE expansion blanking plates and any meshes/filters up top if you feel you need more exhaust space. It's free to try and if you're not happy with the results, you can still add fans later.