I could take a while explaining this...
Think of the weight placed on the structural beams during collapse, and in the events leading up to it. Weak points would have developed, and result in violent stress fractures. Under the heat of the fire, the steel would expand, beyond it's limits, and burst free from it's concrete surrounds - showering concrete out from the building. Some floors also "pancaked" - collapsed. Get a book and sprinkle flour on it. Then drop another book on top. Not only will it make a loud "bang", it will also shoot the flour (or rubble) out of the sides (or windows) due to the air.
Thats just my beliefs above - feel free to question or disprove anything that I have said, or to PM me for my MSN address if anyone wishes to discuss it further.