It's handy to find out the type of XP2000+ you have as there are 4 possible types ...
Pally = Hot, locked and tops out around 1.7ghz XP2100+.
TbredA = Cooler, sometimes unlocked but tops out around 1.9ghz XP2300+.
TbredB = Very cool, unlocked and often top out around 2.25ghz XP2800+.
Thorton = Same as TbredB (essentially a Barton with half the cache disabled). It may be locked, AMD seems to be going that way with it's CPUs.
That gives you a good indication of what your CPU is likely to achieve even though your mobo, RAM and cooling could all limit its potential. What mobo are you running, in particular what chipset? Anyway if you're stable then you're stable and needn't worry about much of this. To ensure you are stable it's a good idea to download Prime95 and run its Torture Test for at least 10 min.
140/35 will give you a decent 5% perf boost, going from XP2000+ to practically XP2200+ is nothing to sniff at anyway, people paid big wads for that not so long ago. Gfx card o/c'ing does yield the best perf increases when it comes to gaming, what gfx card do you use at the mo? Anyway for temp monitoring the best guide is the BIOS closely followed by sw specific to your mobo. Even so they are only rough guides in the first place, mostly good to see what effect a certain o/c or added cooling have on temps than actual temps you're running.