Originally Posted by
peterb
Actually not an endothermic reaction, which is a chemical reaction that requires heat to maintain it (or the reacting chemicals absorb heat, so they feel cold. The opposite is an exothermic\ reaction that gives out heat (the reaction of methane with oxygen for example) However the water (sweat) the body produces does not react with the air. However it does take energy from the skin (heat enerfy) to evaporate the water. This energy is the latent heat of evaporation.
Consider a puddle of water. That will evaportae but requires the input of heat to give a water molecule sufficient energy to leave the liquid phase and enter the gaseous phase. This energy is the latent heat of evaporation, and the water left behind will ose heat (and therefore the temperature will fall) as the water molecules evaporate. The same effect is noticed if you spill alcoho; on your hand - alcohol is more volatile than water (it evaporates more quickly) so your hand feels cold.
As a coroolary - you will get a worse byrn from steam at 100 degrees C than you will from water boiling at 100 degreesc. Although they are at the same teperature, the steam contains more energy (the latent heat of evaporation).