You may find that Dreamweaver has alot of funky features but to mix, match and get all combined and to work whilst looking good takes 3-4 times longer than it would do than writting plain code into a notepad window.
Dont ever use frontpage its terrible (my opinion)
Goto your local library adnd pick up "HTML for beginners" or similar so that you can get the basics.
You will find that even with these "srubbishrubbishrubbishrubbishy - I can do all the code for you" programs that they can NEVER get it exactly how you see in your mind first. This way you need to know what your doing for "tweaking / customising"
Have a look on the net, see if you can find some basic tutorials too, I think you will find you will be a webmaster in no time