Ello. The back fan will help things
As for that Core Temp program: The top half is basically just your processor info. Tells you what it is and stuff. (Frequency is the clock speed, so when you overclock it, you will be able to see the higher frequency in there. And the VID is the amount of Volts running through the CPU - which you may change when you overclock, and if so, you will be able to see it in there.)
The important bits for now though, is just those bottom 3 boxes. Tjunction (i think) tells you how hot the CPU needs to get until it shuts itself down, or atleast slows itself down to protect itself. 100C is surprisingly high, but that may be normal on that chip (or CoreTemp may just be reading it wrong).
Anyway, the bottom two are just the temperatures of each individual core on your CPU (cause its a dual core). So they are both running at 39 degrees celsius. I just checked on the internet, and those temperatures are ok, although a few degrees higher than some people. Good temp seems to be about 29/30 degrees or so, but the majority of people seem to have around 37 or 38 or so. So you are average, or maybe a couple of degrees above. BUT, its important to note:
1) Room temperature has a big effect on CPU's. So if your room is nice and warm, then your temps are really good. If your room is like a fridge, then you are probably like 6 degrees higher than average or something.
2) Temps can go down a few degrees when your thermal compound has had a few days to settle.
3) It could go down more than a few degrees when you add your rear fan to the case.
So basically, it seems like you are doing ok. I would be interested to see what it goes to when you put that rear fan in. But anyway, it all seems ok.
The only other thing you could check, would be what temperature both the cores go to when your PC is running at full load. I think the best program to test that is called "Intel Thermal Analysis Tool". It shows the same temperature as that Core Temp program, but there is a button next to each core, and you can click that to make it push your CPU's to max. And then you can see what temperature it goes up to.
You can get it here:
http://shintai.ambition.cz/files/tat.exe